Australian Natural Resources Atlas

Australian Natural Resources Atlas

Australia

The material below is an extract from the Australian Agriculture Assessment 2001 report. For ease of cross reference, figure, table and section references pertain to the chapter structure of this report. The Further Information section provides links to the full graphics version of the material below and the Australian Agriculture Assessment 2001 report.

Rivers - nutrient loads and transport

SUMMARY

Nutrient sources*

Nutrient exports to receiving waters

Changes in river nutrient loads

* Due to a lack of data, intensive rural industries (e.g. feedlots and piggeries) were not included. However it should be noted that these industries are subject to certification, specific industry guidelines, and are regulated and monitored through State government activities.


INTRODUCTIONPhoto 6.1

Increases in river nutrient loads generally lead to increases in the production of algae and aquatic plants, with follow-on effects up the aquatic food chain. Large nutrient increases typically favour a small number of species at the expense of others, and so while overall system productivity is increased, biodiversity is reduced. The reduced diversity of species is often associated with reduced system resilience, and catastrophic collapses are common. Such collapses may include the death and decay of large algal blooms, thereby increasing biological oxygen demand, lowering dissolved oxygen levels and leading to massive fish kills and high mortality amongst other river fauna (see Australian Catchment, River and Estuary Assessment 2001 for the Audit river and estuary assessments).

River nutrient budgets for phosphorus and nitrogen allow determination of:

They are linked to landscape nutrient budgets, because erosion and surface run-off are important pathways for nutrient loss from the landscape. An understanding of the fate of nutrients lost from landscapes and ecological responses to nutrient loads in the receiving waters, can help guide land and water planning and management.

A modelling approach was developed to combine outputs from erosion and river sediment transport modelling, with landscape-plant-soil-atmosphere-nutrient flux modelling and point source discharge data. River nutrient transport modelling considers dissolved nutrients that are associated with those bound to suspended sediments. Exchanges between these forms are modelled for phosphorus. Losses from transport include:

Modelling river nutrient transport

Agricultural and urban disturbance within a catchment leads to increases in nutrients exported to the river systems. These increased nutrient loads affect river ecosystems, usually in undesirable ways. Assessing changes in nutrient loadings is therefore an important aspect for assessing river condition, and one that highlights the linkages between a river and its catchment.

Assessing river nutrient load is complex-either using measured data or by modelling-because of complex processes involved in nutrient sourcing and transport, and the highly time dependent variability of river flow. Process modelling is usually carried out in conjunction with detailed daily hydrology modelling. However, this is not required for broad-scale assessments of changes, and in any case sufficient data are often not available.

A model of river nutrient transport (Annual Network Nutrient Export-see box) was developed to predict current and pre-European nutrient loads in Australian rivers.

Losses of sediment-bound nutrients occur due to fine sediment deposition and long-term storage on floodplains and in reservoirs. These terms were estimated using the Sediment river Network (SedNet) model (Prosser et al. 2001) and assumed that:

Nutrients not lost from transport by fine sediment deposition or denitrification are exported from the river network. As the Annual Network Nutrient Export model does not represent estuarine nutrient transport and transformations, 'exports' from the river network combines nutrient delivery to estuarine and near-shore marine environments.

Estuary types.

Average net total phosphorus export by Australian Water Resources Council basin.

Average net total nitrogen by export river network

Relative sizes of sources and sinks

Phosphorus sources

Phosphorus sinks

The efficiency of phosphorus delivery varies greatly between the regions.

Nitrogen sources

The sources of sediment for particulate nitrogen were assumed to be the same as those for particulate phosphorus.

Dissolved nitrogen contributes a greater proportion of the total nitrogen source than does dissolved phosphorus of the total phosphorus source.

Nitrogen sinks

Information on the sinks for nitrogen provides valuable guidance for land and stream management. With less of the total nitrogen load transported in particulate forms, the percentage losses to floodplain and reservoir sedimentation are lower.

Average annual total phosphorus export rate by Australian Water Resources Council basin

Average annual total nitrogen export rate by Australian Water Resources Council basin

Area-based nutrient export rates

Mapping total nutrient loads across drainage network links (Figures 6.6, 6.7) shows that the largest rivers generally carry the largest nutrient loads. Dividing these loads by the upstream catchment or basin area provides area-based nutrient export rates. Export rates indicate the differences in nutrient source intensity from:

The highest export rates are generally a result of high erosion rates driven by topography, rainfall and land use.

Average annual total phosphorus export by river network.

Average annual total nitrogen export by river network.

Changes in total nutrient loads

Increases in nutrient load

Across the assesed basins, the average total annual phosphorus load increased 2.8 times relative to pre-European levels.

Significant increases in total phosphorus of between 5 and 10 times have ocurred in the rivers of the large Burdekin, Fitzroy, Burnett, and Brisbane basins in Queensland; nine other smaller basins along the Queensland coast; the Border Rivers, Gwydir and Namoi basins in upper Murray-Darling Basin; and the Greenough and Murchison basins in Western Australia.

Relative increase in average annual total phosphorus loads by Australian Water Resources Council basin.

Relative increase in average annual total nitrogen loads by Australian Water Resources Council basin.

Across the assessed basins the average total annual nitrogen loads increased 2.1 times.

Spatial patterns

Basin averages must be interpreted with care, since increases in nutrient loads are not evenly distributed (Figures 6.11, 6.12). For example, several basins in the New South Wales section of Murray-Darling Basin showed much larger increases in total phosphorus in the upper reaches compared to the lower reaches, because of intense gully erosion along the western slopes of the Great Dividing Range.

Relative increase in average annual total phosphorus loads by river network.

Relative increase in average annual total nitrogen load by river network.

Where nutrient loads have increased by over 3.5 times, it is likely that aspects of the rivers will be substantially degraded:

Percentage of stream length that is degraded by increased average annual total phosphorus loads by Australian Water Resources Council basin.

Percentage of stream length that is degraded by increased average annual total nitrogen loads by Australian Water Resources Council basin.

Not all basins with large increases in river nutrient loading also export large loads. Comparison of river link-averaged values indicates potential impacts on river condition, but does not necessarily translate to equivalent increases in basin export (e.g. the Paroo basin shows a moderate increase in link-averaged phosphorus loading, but does not export phosphorus under the natural or the currently modelled scenario).

Nutrient exports need to be linked back to catchment land uses, because nutrient loss pathways for dissolved and sediment-bound nutrients differ and may require different control practices.

Phosphorus

In the case of phosphorus, exchanges between dissolved (in water) and sediment-bound phosphorus pools occur during transport. The percentage increase in the load that is caused by each of four major source types has been determined (Appendix 1).

Nitrogen


NUTRIENT FORMS AND LIKELY ECOLOGICAL IMPACTS

Nutrient forms

Phosphorus

Particulate phosphorus occurs in organic and inorganic forms (inorganic particulate phosphorus mainly occurs as phosphate ions chemically adsorbed to eroded clay mineral particles)

Dissolved phosphorus is immediately available to aquatic plants and algae, but particulate phosphorus can change into the dissolved form as local water quality conditions change.

Most or all of the phosphorus in transport has the potential to be bio-available in the long term. In the short term, the ability of the suspended sediment in a river to provide phosphorus for algal growth beyond that in the dissolved fraction is described by the relative buffering capacity (Froelich 1988), which is proportional to the inverse of the ratio of dissolved phosphorus to total phosphorus. That is, for low values of this ratio the buffering capacity is high, and for high values of this ratio the buffering capacity is low.

Percentage of average annual total phosphorus load dissolved by Australian Water Resources Council basin.

Percentage of average annual total phosphorus load that is dissolved by river network.

Variation in the ratio of dissolved to total phosphorus (Figures 6.15,6.16) shows a spatial pattern in relative buffering capacity, and hence differences between rivers in their short-term ability to provide phosphorus from suspended sediments for algal growth.

Nitrogen

Most of the particulate nitrogen is organic, although some exists as ammonium chemically bound to sediments.

Dissolved nitrogen is more available to most aquatic plants and algae than other forms, although ammonium is relatively easily stripped from sediments for biological uptake. However, ammonium is only a small fraction of total load and the ratio of the dissolved load to the total nitrogen load is a reasonable indicator of the proportion of the nitrogen load that is readily available to aquatic plants and algae (Figures 6.17, 6.18).

Percentage of average annual total nitrogen loads that is dissolved by Australian Water Resources Council basin.

Percentage of average annual total nitrogen loads that is dissolved by river network.

Nitrogen:phosphorus ratios

The ratio of nitrogen to phosphorus in water indicates their relative availability to aquatic organisms. This ratio in algae approximates to the relative amounts of these two nutrients actually used by the algae.

An expression of the nitrogen to phosphorus ratio is known as the 'Redfield ratio' (Redfield 1958). The 'Redfield ratio'defines a threshold value (approximately 6.8, by weight) which can be used to evaluate the nutrient status of a water body.

Total nitrogen to total phosphorus ratios vary for pre-European conditions from slightly less than 6.8 to nearly 20 (Table 6.6). Where turbidity is not extreme and these ratios are high (e.g. south-west of Western Australia) growth of phytoplankton is likely to be phosphorus limited.

Redfield ratio

When the Redfield ratio is greater than 6.8 the water body is regarded as phosphorus deficient, and when it is less than 6.8 it is regarded as nitrogen deficient. Nitrogen deficient conditions favour those species of algae (including many blue-green algal species) that fix atmospheric nitrogen.

The Redfield ratio must be interpreted with caution because of the differing bio-availability of different nutrient forms under different river conditions. They are only a strong determinant of phytoplankton community structure in situations where population growth is primarily limited by nutrient supply. The ratio is less relevant in very turbid rivers, where phytoplankton growth is mainly limited by light.

RegionCurrent TN/TPNatural TN/TPCurrent/natural TN/TP
Far North Queensland 6.3 8.8 0.77
North Queensland 5.9 9.1 0.70
Burdekin 3.5 6.5 0.59
Fitzroy 4.6 10.3 0.46
Moreton Bay 7.6 15.7 0.49
Queensland South 6.9 14.4 0.49
Murray-Darling Basin 13.2 18.8 0.72
New South Wales North 9.9 17.6 0.57
New South Wales South 10.0 16.3 0.61
Victoria East 16.4 19.8 0.82
Victoria West 17.2 21.0 0.84
South Australia Gulf 21.5 18.2 1.23
Western Australia South 24.7 22.4 1.11
Indian 8.7 21.7 0.52
Tasmania 12.8 15.9 0.86

Relative change in the ratio of average annual total nitrogen load to average annual total phosphorus load by Australian Water Resources Council basin.

Relative change in the ratio of average annual total nitrogen load to average annual total phosphorus load by river network..


IMPLICATIONS FOR LAND AND WATER MANAGEMENT


REFERENCES

Brune G.M. 1953, 'Trap efficiency of reservoirs',Transactions, American Geophysical Union vol. 34, pp. 407 - 418.

Cole R.A. 1973, 'Stream community response to nutrient enrichment', Journal of Water Pollution Control Federation vol. 45, pp. 1875 - 1888.

Edmonson W.T. & Lehman J.R. 1981, 'The effect of changes in nutrient income on the conditions of Lake Washington', Limnology and Oceanography vol. 26, pp. 1 - 28.

Froelich P.N. 1988, 'Kinetic control of dissolved phosphate in natural rivers: a primer on the phosphate buffer mechanism', Limnology and Oceanography vol. 33, pp. 649 - 668.

Prosser I.P., Hughes A.O., Rustomji P., Young W. & Moran C.J. 2001, Assessment of River Sediment Budgets for the National Land and Water Resources Audit, CSIRO Land and Water Technical Report xx/01 (in press), Canberra.

Redfield A.C. 1958, 'The biological control of chemical factors in the environment', American Scientist vol. 46, pp. 205 - 222.

Schindler D.W., Armstrong F.A.J., Holmgren S.K. & Brunskill G.J. 1971, 'Eutrophication of Lake 227, Experimental Lakes area, Northwest Ontario, by addition of phosphorus and nitrate', Journal of the Fisheries Research Board Canada vol. 28, pp. 1763 - 1782.

Vollenweider R.A. 1992, 'Coastal marine eutrophication: principles and control', in R.A. Vollenweider, R. Marchetti & R. Viniani (eds), Marine Coastal Eutrophication, Science of the Total Environment Supplement, Elsevier, Amsterdam.

Further information

View the Australian Agriculture Assessment 2001 report.

View the river nutrient loads and transport chapter of the Australian Agriculture Assessment 2001 (theme) report.

A range of technical reports have been prepared by CSIRO Land and Water in the development of this work on river nutrient loads and transport: nutrient loads in river networks;regionalisation of flows

Nutrient loads in river networks

As a part of the National Land and Water Resources Audit (NLWRA), sediment and nutrient transport were modelled in large-scale networks across Australia. This report describes the nutrient transport model and its validation at the national scale. The model - ANNEX (Annual Network Nutrient Export) is a static model that predicts the average annual loads of phosphorus and nitrogen in each link in a river network under given catchment conditions. ANNEX is based on a node-link representation of a river network and because of its dependence on the suspended sediment budget, it is run in conjunction with the SedNet model (Prosser et al., 2001) For each link ANNEX requires values for the sediment-bound and dissolved nutrient inputs from the immediate catchment of the link. ANNEX then routes nutrient loads through the river network estimating the losses associated with floodplain and reservoir sedimentation and instream denitrification. While the sediment-bound and dissolved nitrogen budgets are calculated separately, for phosphorus, the exchanges between the sediment-bound and dissolved phases during transport are modelled.

ANNEX has been calibrated for "current conditions" at a national scale using nutrient load estimates from flow and water quality measurements at 93 stations. Improved predictions of nutrient loads at a regional or catchment scale are probably attainable by calibrating to local load estimates, and by using better local input data.

View or download a technical report on " Modelling nutrient loads in large-scale river networks " by W.J. Young, I.P. Prosser, and A.O. Hughes (PDF 0.6 MB)

Regionalisation of flows

As a part of the National Land and Water Resources Audit, sediment and nutrient transport were modelled in large-scale river networks across Australia. These models required estimates of a number of hydrologic variables for each link in the river network. To provide these estimates, simple hydrologic regionalisation models were developed. These models predict the required hydrologic variables as functions of drainage area to the network link and the mean annual rainfall spatially-averaged across this drainage area. The hydrologic data used to build the models were a mixture of modelled daily flows and observed daily flows. The primary model that was developed is used to estimate the mean annual flow in a network link. Mean annual flow models were developed for three different regions of Australia defined by similarity of mean annual runoff coefficients. The models vary in robustness between regions, partly as a result of different size data sets. The mean annual flow models are for drainage areas between 50 km² and 2000 km². Values for links with larger drainage areas were estimated by linear interpolation between the regionalised values and AWRC basin outflow estimates. Secondary models were developed to predict the median daily flow, the bankfull flow, the median over-bank flow, and a parameterised function of daily flows used to estimate sediment transport capacity. These secondary models were all functions of the mean annual flow. While most of these variables are reasonably predicted by mean annual flow, the median daily flow (which for the highly skewed flow distributions of most Australian rivers is an indicator of typical low flow conditions) is poorly predicted by mean annual flow. Predictors other than drainage area and mean annual rainfall are required to build more robust regionalisation models for median daily flow.

Further Information

Key

   Links to an another web site
   Opens a pop-up window